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Link to original content: https://pubmed.ncbi.nlm.nih.gov/18271535
On the 2-electron 3-center B-H-B bond: charge density determination of tetraborane(10) - PubMed Skip to main page content
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. 2008 Mar 17;47(6):1874-6.
doi: 10.1021/ic701924r. Epub 2008 Feb 14.

On the 2-electron 3-center B-H-B bond: charge density determination of tetraborane(10)

Diana Förster  1 , Christian B Hübschle, Peter Luger, Thomas Hügle, Dieter Lentz
Affiliations

On the 2-electron 3-center B-H-B bond: charge density determination of tetraborane(10)

Diana Förster et al. Inorg Chem. .

Abstract

In order to characterize the 2-electron 3-center hydride bridges in arachno-tetraborane, an experimental charge-density study was performed complemented with various theoretical calculations. The charge-density distribution and its topological properties were analyzed according to the "atoms in molecules" theory of Bader. The asymmetric bonding situation of the highly polarized hydride bridges is discussed in detail.

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