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Hermann Guenther (1850–1851) • Eduardo Schroeder (1851–1852) • Benno von Frankenberg-Ludwigsdorf (1852–1855) • Léonce Aubé (1856–1860) • Johann Otto Louis Niemeyer (1860–1873) • Frederico Bruestlein (1875)

Período monárquico

João Adolfo Haltenhoff (1869–1873) • Ottokar Doerffel (1874–1877) • Augusto Stock (1877–1881) • Carlos Monich (1877) • Vitorino de Sousa Bacelar (1881–1883) • Francisco Machado da Luz • João Paulo Schmalz (1883–1887) • Frederico Bruestlein (1887–1890)

Período republicano

Século XIX	Ernesto Canac (1890–1892) • Abdon Batista (1892–1893) • Abdon Batista (1893–1894) • João Paulo Schmalz (1894–1895) • Frederico Bruestlein (1895–1899) • Gustavo Adolfo Richlin (1899–1903)
Século XX	Otto Boehm (1901–1902) • Procópio Gomes de Oliveira (1903–1907) • Oscar Antônio Schneider (1907–1910) • Procópio Gomes de Oliveira (1911–1914) • Abdon Batista (1915–1921) • Marinho P. de Sousa Lobo (1922–1926) • Plácido Olímpio de Oliveira (1930–1933) • Max Colin (1934–1936) • Aristides Largura (1936–1938) • Nabor de Lima Monteiro (1939–1940) • Arnaldo Moreira Douat (1940–1944) • Geraldo Wetzel (1947) • João Herbert Érico Colin (1947–1950) • João Herbert Érico Colin (957–1957) • Dario Geraldo Sales (1957–1958) • Baltasar Buschle (1958–1961) • Helmut Fallgatter (1961–1966) • Nilson Wilson Bender (1966–1970) • Harald Karmann (1970–1973) • Pedro Ivo Campos (1973–1977) • Luiz Henrique da Silveira (1977–1982) • Wittich Freitag (1983–88, 93-96) • Luiz Henrique da Silveira (1997–2002)
Século XXI	Marco Tebaldi (2002–2008) • Carlito Merss (2009–2012) • Udo Döhler (2013–2020) • Adriano Silva (2021–presente)