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Link to original content: http://dbpedia.org/data/Silicalite.json
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It is one of several forms (polymorphs) of silicon dioxide. It is a white solid. It consists of tetrahedral silicon centers and two-coordinate oxides. It is prepared by hydrothermal reaction using tetrapropylammonium hydroxide followed by calcining to remove residual ammonium salts. The compound is notable in being ca. 33% porous. It is useful because the material contains (SiO)10 rings that allow sorption of hydrophobic molecules of diameter 0.6 nm." , "lang" : "en" } ] , "http://xmlns.com/foaf/0.1/depiction" : [ { "type" : "uri", "value" : "http://commons.wikimedia.org/wiki/Special:FilePath/EntryWithCollCode34370.png" } ] , "http://purl.org/dc/terms/subject" : [ { "type" : "uri", "value" : "http://dbpedia.org/resource/Category:Polymorphism_(materials_science)" } ] , "http://dbpedia.org/ontology/abstract" : [ { "type" : "literal", "value" : "Silicalite is an inorganic compound with the formula SiO2. It is one of several forms (polymorphs) of silicon dioxide. It is a white solid. It consists of tetrahedral silicon centers and two-coordinate oxides. It is prepared by hydrothermal reaction using tetrapropylammonium hydroxide followed by calcining to remove residual ammonium salts. The compound is notable in being ca. 33% porous. It is useful because the material contains (SiO)10 rings that allow sorption of hydrophobic molecules of diameter 0.6 nm. A commercially important modification of silicalite is titanium silicalite. With the formula Si1\u2212xTixO2, it consists of silicalite with Ti doped into some Si sites. Unlike conventional polymorphs of titanium dioxide, the Ti centers in titanium silicalite have tetrahedral coordination geometry. The material is a useful catalyst for the reaction of hydrogen peroxide with propylene to give propylene oxide." , "lang" : "en" } ] , "http://dbpedia.org/ontology/wikiPageWikiLink" : [ { "type" : "uri", "value" : "http://dbpedia.org/resource/Propylene_oxide" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Polymorphism_(materials_science)" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Inorganic_compound" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Titanium_dioxide" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Silicon_dioxide" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Category:Polymorphism_(materials_science)" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Hydrogen_peroxide" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Propylene" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Nanometer" } ] , "http://dbpedia.org/property/wikiPageUsesTemplate" : [ { "type" : "uri", "value" : "http://dbpedia.org/resource/Template:Materials-sci-stub" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Template:Chembox_Identifiers" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Template:Silica_minerals" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Template:Chembox_Hazards" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Template:Chembox_Properties" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Template:Chembox" } ] , "http://dbpedia.org/ontology/thumbnail" : [ { "type" : "uri", "value" : "http://commons.wikimedia.org/wiki/Special:FilePath/EntryWithCollCode34370.png?width=300" } ] , "http://dbpedia.org/ontology/wikiPageRevisionID" : [ { "type" : "literal", "value" : 1098408277 , "datatype" : "http://www.w3.org/2001/XMLSchema#integer" } ] , "http://dbpedia.org/ontology/wikiPageLength" : [ { "type" : "literal", "value" : "2214" , "datatype" : "http://www.w3.org/2001/XMLSchema#nonNegativeInteger" } ] , "http://dbpedia.org/ontology/wikiPageID" : [ { "type" : "literal", "value" : 58603248 , "datatype" : "http://www.w3.org/2001/XMLSchema#integer" } ] , "http://www.w3.org/2002/07/owl#sameAs" : [ { "type" : "uri", "value" : "https://global.dbpedia.org/id/5Umnv" } , { "type" : "uri", "value" : "http://dbpedia.org/resource/Silicalite" } , { "type" : "uri", "value" : "http://ta.dbpedia.org/resource/\u0B9A\u0BBF\u0BB2\u0BBF\u0B95\u0BCD\u0B95\u0BBE\u0BB2\u0BC8\u0B9F\u0BCD\u0B9F\u0BC1" } , { "type" : "uri", "value" : "http://www.wikidata.org/entity/Q56811200" } ] , "http://www.w3.org/ns/prov#wasDerivedFrom" : [ { "type" : "uri", "value" : "http://en.wikipedia.org/wiki/Silicalite?oldid=1098408277&ns=0" } ] , "http://xmlns.com/foaf/0.1/isPrimaryTopicOf" : [ { "type" : "uri", "value" : "http://en.wikipedia.org/wiki/Silicalite" } ] , "http://dbpedia.org/property/imagesize" : [ { "type" : "literal", "value" : 284 , "datatype" : "http://www.w3.org/2001/XMLSchema#integer" } ] , "http://dbpedia.org/property/imagefile" : [ { "type" : "literal", "value" : "EntryWithCollCode34370.png" , "lang" : "en" } ] } , "http://dbpedia.org/resource/Zeolite" : { "http://dbpedia.org/ontology/wikiPageWikiLink" : [ { "type" : "uri", "value" : "http://dbpedia.org/resource/Silicalite" } ] } , "http://dbpedia.org/resource/Propylene_oxide" : { "http://dbpedia.org/ontology/wikiPageWikiLink" : [ { "type" : "uri", "value" : "http://dbpedia.org/resource/Silicalite" } ] } , "http://dbpedia.org/resource/Geology_of_Fujian" : { "http://dbpedia.org/ontology/wikiPageWikiLink" : [ { "type" : "uri", "value" : "http://dbpedia.org/resource/Silicalite" } ] } }